Product ID:50-717 BALCK TREE(D-170)
MSDS Date:04/30/1993
FSC:8010
NIIN:01-273-9347
MSDS Number: BTSJW

NILES CHEMICAL PAINT CO.

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 219-236-5856

Info Phone: 616-683-3377

Preparer: MIKE LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

STODDARD SOLVENT

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 45%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM; 9394

ALKYD RESIN

Fraction By Weight: 14%

#100 SOLVENT [NAPHTHA, LIGHT AROMATIC]

CAS: 64742-95-6

Fraction By Weight: 3%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM 9091

COBALT (SARA III),DUST AND FUME

CAS: 7440-48-4

RTECS: GF8750000

Fraction By Weight: <1%

OSHA PEL 0.1 MG/M3

ACGIH TLV: 0.05 MG/M3;DUST 9394

MANGANESE (SARA III)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: <1%

OSHA PEL C 5 MG/M3 DUST

ACGIH TLV: 5 MG/M3 DUST 9394

PROPRIETARY INGREDIENTS [MFR STATES THAT THESE INGREDIENTS

Fraction By Weight: BALANCE

4.75 LBS/GAL

RTECS: 9999999VO

HYDROCARBON PROPELLANT

CAS: 68476-86-8

Fraction By Weight: 22%

ACGIH TLV: 900 PPM (PER MFG)

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION MAY CAUSE NASAL &
RESPIRATORY IRRITATION,CNS DEPRESSION.CONTACT MAY CAUSE SKIN & EYE
IRITATION.MAY BE HARMFUL IF SKIN ABSORBED.INGESTION MAY CAUSE
GASTROINTESTINAL IRRITATION.CHRONIC :PROLONGED OR REPEATED EXPOSURE
MAY CAUSE UNCONSCIOUSNESS,COMA,DEATH FROM SUFFOCATION.TARGET
ORGANS:LUNGS,CNS,EYES,SKIN
Explanation of Carcinogenicity:NO INGREDIENTS OF A CONCENTRATION OF
0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:INHALED: DIZZINESS, DROWSINESS, HEADACHE,
NAUSEA, VOMITING, WEAKNESS, FATIGUE, CONFUSION, SHORTNESS OF
BREATH. EYES: LACRIMATION, REDNESS, BLURRED VISION, BURNS, VISUAL
DISTURBANCES. SKIN: REDNESS, DE FATTING, ITCHING, DISCOMFORT.
INGESTED:ABDOMINAL PAIN, NAUSEA, VOMITING, DIARRHEA.
Medical Cond Aggravated by Exposure:NONE KNOWN.

First Aid:INHALED-REMOVE TO FRESH AIR. IF BREATHING STOPPED, GIVE
ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION IMMEDIATELY.
SKIN-WASH WITH SOAP AND WATER. EYES-FLUSH WITH WATER FOR 15
MINUTES, LIFT LIDS. GET I MMEDIDATE MEDICAL ATTENTION.
SWALLOWING-DO NOT INDUCE VOMITING! IF CONSCIOUS, GIVE 1-2 GLASSES
OF WATER. CALL DOCTOR OR POISON CONTROL CENTER IMMEDIATELY. TREAT
SYPMTOMATICALLY.

Flash Point Method:TCC
Flash Point:-99F,-73C
Lower Limits:0.8
Upper Limits:36
Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WITH
FULL-FACEPIECE & FULL PROTECTIVE CLOTHING.WATER MAY BE USED TO COOL
CLOSED CONTAINERS TO PREVENT RUPTURE/EXPLOSION.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. DURING EMERGENCY CONDITIONS, OVEREXPOSURE
TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARDS.

Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION.MINIMIZE THE
BREATHING OF VAPORS & AVOID SKIN CONTACT.ABSORB WITH INERT MATERIAL
SUCH AS CLAY,SOIL,OR A COMMERCIALLY AVAILABLE ABSORBENT.SHOVEL
RECLAIMED LIQUID & ABS ORBENT INTO RECOVERY OR SALVAGE DRUM FOR
DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID STORAGE IN HIGH TEMPERATURE
AREAS OR NEAR FIRE OR OPEN FLAME. KEEP CONTAINERS CLOSED WHEN NOT
IN USE. AVOID ROUGH HANDLING.
Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN
EMPTY. DO NOT WELD OR FLAME CUT EMPTY DRUMS. CONTACT LENSES SHOULD
NOT BE WORN WHEN WORKING WITH THIS MATERIAL.

Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR EMERGENCY
OCCURS; USE NIOSH/MSHA APPROVED RESPIRATOR OR SUPPLIED AIR
RESPIRATOR OR SCBA, AS REQUIRED. USE IN ACCORDANCE WITH 29 CFR
1910.134.
Ventilation:SUFFICIENT VENTILATION IN VOLUME & PATTERN SHOULD BE
PROVIDED TO KEEP EXPOSURE BELOW OSHA PEL.
Protective Gloves:NITRILE OR VITON
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES
Other Protective Equipment:CLOTHING AS NEEDED TO PREVENT SKIN CONTACT.
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING, OR USING
RESTROOM. REMOVE & LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
MSDS ENTERED BY DLA-HMIS UNDER PROJECT FOR GSA.

HCC:V3
Boiling Pt:B.P. Text:>-10F,>-23C
Vapor Density:>1
Spec Gravity:0.797
Evaporation Rate & Reference:<1 (ETHER=1)
Solubility in Water:APPRECIABLE
Appearance and Odor:LIQUID; SOLVENT ODOR
Percent Volatiles by Volume:83.68
Corrosion Rate:MIMIMAL

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS SUCH AS CHLORINE, PERMANGANATES AND
DICHROMATES.
Stability Condition to Avoid:HIGH TEMPERATURES, SHOCK FRM DROPPING
Hazardous Decomposition Products:CAN PRODUCE CARBON MONOXIDE AND CARBON
DIOXIDE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. EPA SECTION 311/312-IMMEDIATE(ACUTE)HEALTH
HAZARD;DELAYED(CHRONIC);FIRE;SUDDEN RELEASE OF PRESSURE.SECTION 313
(40 CFR 372)-METHANOL ,MANGANESE CMPDS,COBALT CMPDS.SECTION 302- NO
EHS

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of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.